Molecular Doping of Porous Organic Cages

摘要

Porous organic cages can act as hosts for the three-dimensional alignment of guests such as halogens and organometallics. Porous single crystals are doped by vapor sublimation to produce diamondoid arrangements of guests such as I_5~- and OsO_4, leading to marked conductivity enhancement in the case of I_5~-.