• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of the American Chemical Society >A Sodalite-Type Porous Metal-Organic Framework with Polyoxometalate Templates: Adsorption and Decomposition of Dimethyl Methylphosphonate
【24h】

A Sodalite-Type Porous Metal-Organic Framework with Polyoxometalate Templates: Adsorption and Decomposition of Dimethyl Methylphosphonate

机译：具有多金属氧酸盐模板的方钠石型多孔金属有机骨架：甲基膦酸二甲酯的吸附和分解

获取原文
获取原文并翻译 | 示例
       
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A sodalite-type porous metal-organic framework with polyoxometalate templates, H_3[(Cu_4Cl)_3(BTC)_8]_2-[PW_(12)O_(40)]·(C_4H_(12)N)_6·3H_2O (NENU-11; BTC = 1,3, 5-benzenetricarboxylate), was obtained by a hydrothermal reaction. As a reasonable candidate for eliminating nerve gas, NENU-11 displays good adsorption behavior for dimethyl methylphosphonate (15.5 molecules per formula unit). In virtue of the catalytic activity of polyoxometalate guests, this nerve gas mimic could be facilely decomposed by a hydrolysis reaction.
机译：具有多金属氧酸盐模板的方钠石型多孔金属有机骨架H_3 [（Cu_4Cl）_3（BTC）_8] _2- [PW_（12）O_（40）]·（C_4H_（12）N）_6·3H_2O（NENU-通过水热反应获得11； BTC ＝ 1，3，5-苯三羧酸酯。作为消除神经毒气的合理候选者，NENU-11对甲基膦酸二甲酯具有良好的吸附性能（每个配方单位15.5个分子）。由于多金属氧酸盐客体的催化活性，该神经气体模拟物可以通过水解反应容易地分解。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2011年第12期|p.4178-4181|共4页
  • 作者

    Feng-Ji Ma; Shu-Xia Liu; Chun-Yan Sun; Da-Dong Liang; Guo-Jian Ren; Feng Wei; Ya-Guang Chen; Zhong-Min Su;

  • 作者单位

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

    Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University,Changchun, Jilin 130024, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

  • 入库时间 2022-08-18 03:14:11

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号