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Deoxygenation of Ethers To Form Carbon-Carbon Bonds via Nickel Catalysis

机译:通过镍催化使醚脱氧以形成碳-碳键

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摘要

In this article a successful protocol was developed to construct carbon-carbon bonds by the extrusion of the O atom of ethers via nickel catalysis in the presence of reductants. This methodology is featured as a highly economic route to construct sp~3-sp~3 C-C bonds through dual C-O activation of ethers with good functional group tolerance.
机译:在本文中,开发了一种成功的方案,可通过在还原剂存在下通过镍催化将醚的O原子挤出来构建碳-碳键。该方法的特点是通过具有良好官能团耐受性的醚的双重C-O活化来构建sp〜3-sp〜3 C-C键的经济途径。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2017年第19期|6546-6549|共4页
  • 作者

    Zhi-Chao Cao; Zhang-Jie Shi;

  • 作者单位

    College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;

    College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China,Department of Chemistry, Fudan University, Shanghai 200433, China,State Key Laboratory of Organometallic Chemistry, Chinese Academy of Science, Shanghai 200032, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

  • 入库时间 2022-08-18 03:07:58

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