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首页> 外文期刊>Journal of the American Chemical Society >Construction of Porphyrin-Containing Metallacycle with Improved Stability and Activity within Mesoporous Carbon
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Construction of Porphyrin-Containing Metallacycle with Improved Stability and Activity within Mesoporous Carbon

机译：具有改善的介孔碳内稳定性和活性的含卟啉金属环的构建

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摘要

The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C ) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, ~(1)O_(2) generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.
机译：这项研究提出了卟啉官能化金属环在中孔碳FDU-16（3⊂C）的密闭腔中的成功构建。由于金属环化合物在介孔腔内的高度分散，含卟啉金属环化合物的稳定性和活性得到明显改善。例如，3⊂C的〜（1）O_（2）生成效率约为。比溶液中的游离金属分子快6倍。因此，所得杂化材料已成功地用作硫化物光氧化的非均相催化剂。

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  • 来源
    《Journal of the American Chemical Society》 |2018年第15期|5049-5052|共4页
  • 作者

    Li-Jun Chen; Shangjun Chen; Yi Qin; Lin Xu; Guang-Qiang Yin; Jun-Long Zhu; Fan-Fan Zhu; Wei Zheng; Xiaopeng Li; Hai-Bo Yang;

  • 作者单位

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

    Department of Chemistry, Shanghai Normal University, Shanghai 200234, People’s Republic of China;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China,Department of Chemistry, University of South Florida Tampa, Florida 33620, United States;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

    Department of Chemistry, University of South Florida Tampa, Florida 33620, United States;

    Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chang-Kung Chuang Institute, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, People’s Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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  • 正文语种 eng
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  • 入库时间 2022-08-18 03:07:20

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