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首页> 外文期刊>Journal of testing and evaluation >The Atom Transfer Radical Polymerization of Methyl Methacrylate in Ionic Liquid Media of 1-Methylimidazolium Alkyltes
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The Atom Transfer Radical Polymerization of Methyl Methacrylate in Ionic Liquid Media of 1-Methylimidazolium Alkyltes

机译：1-甲基咪唑鎓烷基醇在离子液体介质中甲基丙烯酸甲酯的原子转移自由基聚合

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摘要

Three br?nsted acidic ionic liquids, 1-methylimidazolium acetate ([Hmim][CH3COO]), 1-methylimidazolium propionate ([Hmim][CH3CH2COO]) and 1-methylimidazolium butyrate ([Hmim][CH3CH2CH2COO]) were used as reaction medium for atom transfer radical polymerization of methyl methacrylate with ethyl 2-bromoisobutyrate (EBiB)/CuBr as the initiating system. Kinetic studies, chain extension and block copolymerization confirmed the well-controlled manner of these polymerizations in three bronsted acidic ionic liquids. The reactions were fast and the polydispersities of the polymers were quite narrow (1.10
机译：三种布朗斯台德酸性离子液体，乙酸1-甲基咪唑鎓（[Hmim] [CH3COO]），1-甲基咪唑丙酸（[Hmim] [CH3CH2COO]）和1-甲基咪唑丁酸（[Hmim] [CH3CH2CH2COO]）介质用于甲基丙烯酸甲酯的原子转移自由基聚合，以2-溴异丁酸乙酯（EBiB）/ CuBr为引发体系。动力学研究，链增长和嵌段共聚证实了在三种布朗斯台德酸性离子液体中这些聚合反应的良好控制方式。反应快速并且聚合物的多分散性非常窄（1.10

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  • 来源
    《Journal of testing and evaluation》 |2011年第5期|p.967|共1页
  • 作者

    Fumin Ma; Wen Li; Guoqiao Lai; Jianlin Guo; Min Ruan; Wanguang Qin;

  • 作者单位

    Hubei Key Laboratory of Environmental Pollution Control and Resources Reuse and School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi 435003, People's Republic of China;

    Hubei Key Laboratory of Environmental Pollution Control and Resources Reuse and School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi 435003, People's Republic of China;

    Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012,China;

    Hubei Key Laboratory of Environmental Pollution Control and Resources Reuse and School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi 435003, People's Republic of China;

    Hubei Key Laboratory of Environmental Pollution Control and Resources Reuse and School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi 435003, People's Republic of China;

    Hubei Key Laboratory of Environmental Pollution Control and Resources Reuse and School of Chemical and Materials Engineering, Huangshi Institute of Technology, Huangshi 435003, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    br?nsted acidic ionic liquids; ATRP; 1-methylimidazolium carboxylate;

    机译：布朗斯台德酸性离子液体;ATRP;1-甲基咪唑羧酸盐;
  • 入库时间 2022-08-17 13:35:27

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