Recent advances in synthesis and analysis of Fe(VI) cathodes: solution phase and solid-state Fe(VI) syntheses, reversible thin-film Fe(VI) synthesis, coating-stabilized Fe(VI) synthesis, and Fe(VI) analytical methodologies

摘要

Fe(VI) batteries based on unusual ferrate cathodic charge storage have been studied for quite a few years. So far, a class of Fe(VI) compounds have been successfully synthesized and studied as the cathodic materials in both alkaline and nonaqueous battery systems. This paper provides a summary of the syntheses of a range of Fe(VI) cathodes including the alkali Fe(VI) salts Li2FeO4, K x Na(2?x)FeO4, K2FeO4, Rb2FeO4, Cs2FeO4, as well as alkali earth Fe(VI) salts CaFeO4, SrFeO4, BaFeO4, and a transition metal Fe(VI) salt Ag2FeO4. Two synthesis routes summarized in this paper are the solution phase synthesis and the solid-state synthesis. Preparation of coating-stabilized (coated with KMnO4, SiO2, TiO2, or ZrO2) Fe(VI) cathodes and preparation of thin-film reversible Fe(VI/III) cathodes are also presented. Fe(VI) analytical methodologies summarized in this paper include Fourier transform infrared spectrometry, titrimetric (chromite), ultraviolet-visible spectroscopy, X-ray diffraction, inductively coupled plasma spectroscopy, M?ssbauer spectrometry, potentiometric, galvanostatic, and cyclic voltammetry. Cathodic charge transfer of Fe(VI) is also briefly presented.