Preparation and electrochemical performance of activated carbon thin films with polyethylene oxide-salt addition for electrochemical capacitor applications

摘要

The effect of polymer–salt addition in the activated carbon electrode for electric double-layer capacitor (EDLC) has been investigated. A series of composite thin film electrode consisting of activated carbon, carbon black, polytetrafluoroethylene and polymer–salt complex (polyethyleneoxide–LiClO4) with an appropriate weight ratio were prepared and examined their performance for EDLCs using 1 mol L?1 LiClO4 in ethylene carbonate:diethylcarbonate electrolyte solution. The electrochemical capacitance performances of these electrodes with different compositions were characterized by cyclic voltammetry, galvanostatic charge–discharge cycling, and AC impedance measurements. By comparison, the best results were obtained with a composite electrode rich in polymer–salt additive (132 F g?1 at 100 mA g?1 of galvanostatic experiment). In general, the polymer–salt-containing electrode had shown improved performance over activated carbon electrodes without polymer–salt at high current density.