INTERACTION OF ALDEHYDE DEVELOPED FROM AMINO ACIDS OF TANNERY WASTE IN A LOWER- CHROME TANNAGE: AN ECO-FRIENDLY APPROACH

摘要

The leather industry is categorized as a polluting industry because of the large chemical usage and the generation of solid wastes. It is estimated that as much as 62-75% of the skins appears as solid waste. Fleshings generated in the liming process constitute 50-60% of the total solid waste generated in the industry. In the present study we have attempted the conversion of the fleshings into a useful cross-linking agent, we hydrolysed the fleshings with a proteolytic enzyme in laboratory trials and then carried out further breakdown to the amino acid level before preparing the corresponding aldehyde. The cross-linking agent thus obtained was applied to leather and interacted with chrome to produce a lower-chromium tannage. Shrinkage temperature, differential scanning calorimetry, H NMR, FT-IR and colour matching studies were carried out on the leathers which showed that lower amounts of chrome are sufficient to give improved leather characteristics. The results showed a COD reduction of 58% and chrome exhaustion increased from 69 to 95% both in comparison to a conventional chrome tanning process.