首页> 外文期刊>The Journal of Organic Chemistry >Tandem enyne allene-radical cyclization: low-temperature approaches to benz[e]indene and indene compounds
【24h】

Tandem enyne allene-radical cyclization: low-temperature approaches to benz[e]indene and indene compounds

机译:串联烯炔丙二烯自由基环化:苯并[e]茚和茚化合物的低温方法

获取原文
获取原文并翻译 | 示例
       

摘要

In an effort to lower the temperatures required to prepare multicyclic compounds using the tandem enediyne-radical cyclization, we have developed the tandem enyne allene-radical cyclization which proceeds at temperatures as low as 37 deg C. The reactions were carried out using three different methods for the preparation of the enyne allenes. The first method involved the [3,3] sigmatropic rearrangement of an enediyne followed by a tandem enyne allene-radical cyclization.
机译:为了降低使用串联烯二炔-自由基环化制备多环化合物所需的温度,我们开发了串联烯炔-丙二烯-自由基环化反应,该反应在低至37℃的温度下进行。反应使用三种不同的方法进行用于制备烯炔异戊烯。第一种方法涉及烯二炔的[3,3]σ重排,然后是串联烯炔-异戊二烯-自由基环化。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号