SYNTHESIS AND STRUCTURAL PROPERTIES OF TWO BISCYCLOPROPENES

Golobish TD; Dailey WP

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SYNTHESIS AND STRUCTURAL PROPERTIES OF TWO BISCYCLOPROPENES

机译：两种双环丙烯的合成与结构性质

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The synthesis of two biscyclopropenes, 1 and 2, are described. Both compounds are moderately sensitive to oxygen and Lewis acids. The conformational properties of 1 were examined by dynamic H-1 NMR spectroscopy. The structure of 2 was determined by low-temperature X-ray crystallography. Ab initio calculations successfully reproduce the structure for 2 and the conformational properties of 1.

机译：描述了两种双环丙烯1和2的合成。两种化合物对氧和路易斯酸均中等敏感。通过动态H-1 NMR光谱检查了1的构象性质。通过低温X射线晶体学确定2的结构。从头算计算成功地重现了2的结构和1的构象性质。

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来源
《The Journal of Organic Chemistry》 |1995年第24期|p.7865-7869|共5页
作者
Golobish TD; Dailey WP;
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作者单位

Dailey WP, UNIV PENN, DEPT CHEM, PHILADELPHIA, PA 19104, USA;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Rings;

机译：戒指;
入库时间 2022-08-18 00:04:05

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SYNTHESIS AND STRUCTURAL PROPERTIES OF TWO BISCYCLOPROPENES

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