1,2-Dibromotetrachloroethane: An Ozone-Friendly Reagent for the in Situ Ramberg?Ba?cklund Rearrangement and Its Use in the Formal Synthesis of E?Resveratrol

Stefan C. Söderman and Adrian L. Schwan

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1,2-Dibromotetrachloroethane: An Ozone-Friendly Reagent for the in Situ Ramberg?Ba?cklund Rearrangement and Its Use in the Formal Synthesis of E?Resveratrol

机译：1,2-二溴四氯乙烷：原位Ramberg？Ba？cklund重排的臭氧友好试剂及其在E？白藜芦醇的形式合成中的应用

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Dibromotetrachloroethane (C2Br2Cl4) is demonstrated as anhalogenating reagent for the one-pot conversion of sulfones to alkenes by way ofnthe Ramberg−Bäcklund rearrangement. Dibromotetrachloroethane successfullynreplaces known ozone depleting agents CCl4, CBr2F2 and C2Br2F4. A formalnsynthesis of E-resveratrol is demonstrated using C2Br2Cl4.

机译：二溴四氯乙烷（C2Br2Cl4）被证明是通过Ramberg-Bäcklund重排将砜一锅转化为烯烃的卤化试剂。二溴四氯乙烷成功替代了已知的臭氧消耗剂CCl4，CBr2F2和C2Br2F4。使用C2Br2Cl4证实了E-白藜芦醇的甲醛合成。

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来源
《The Journal of Organic Chemistry》 |2012年第23期|10978-10984|共7页
作者
Stefan C. Söderman and Adrian L. Schwan;
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作者单位

Department of Chemistry University of Guelph Guelph Ontario N1G 2W1 Canada;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
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入库时间 2022-08-17 13:29:35

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1. 1,2-dibromotetrachloroethane: An ozone-friendly reagent for the in situ Ramberga-B?cklund rearrangement and its use in the formal synthesis of E-resveratrol [J] . Soì?derman S.C., Schwan A.L. The Journal of Organic Chemistry . 2012,第23期

机译：1,2-二溴四氯乙烷：一种用于原位Ramberga-B？cklund重排的臭氧友好试剂，其用于E-白藜芦醇的正式合成中
2. Ramberg-B(a)cklund Rearrangement Approaches to the Synthesis of Natural Bibenzyls [J] . WANGXiao-Long(王小龙), LIUDong(刘冬), XIAYa-Mu(夏亚穆), 中国化学（英文版） . 2004,第005期

机译：Ramberg-B（a）cklund重排方法合成天然联苄
3. 1,2-Dibromotetrachloroethane: an efficient reagent for many transformations by modified Appel reaction [J] . SEL?UK E?S?Z, AR?F DA?TAN Turkish journal of chemistry . 2019,第1期

机译：1,2-二溴四氯乙烷：通过改良的Appel反应可进行许多转化的有效试剂
4. Synthesis and Antibacterial Activity of Resveratrol Derivatives [C] . Yuanmou Chen, Fei Hu, Yinghao Gao, International symposium on IT in medicine and education . 2014

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1,2-Dibromotetrachloroethane: An Ozone-Friendly Reagent for the in Situ Ramberg?Ba?cklund Rearrangement and Its Use in the Formal Synthesis of E?Resveratrol

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