The comparison of two electrochemical process models involving chemical steps

摘要

In this paper the comparison of two models of the same electrochemical process involving chemical steps has been made with the aim of accomplishing two tasks: (1) the analysis of concentration of each of components taking part in the electrochemical process, and (2) the analysis of the total metal or total ligand concentration. An assumption that the increase of the system lability makes the two systems’ solutions close was tested out. The numerical investigation was proposed. The suggestions for finding the values of parameters giving the same concentrations were made by computational experiments. Keywords Electrochemical reaction - Electrically active complex - Chemical equilibrium - Ligand