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Electrochemical performance of lanthanum cerium ferrite nanoparticles for supercapacitor applications

机译:用于超级电容器应用的镧铈铁氧体纳米粒子的电化学性能

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摘要

Lanthanum cerium ferrite nanoparticles has been synthesized for the first time via hydrothermal and co-precipitation method. The structural and morphological study of the nanoparticles have been examined using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). The electrochemical study of J1 and J2 electrodes have been examined using three electrode system in 6 M KOH electrolyte using cyclic voltammetry (CV), gal-vanostatic charging-discharging (GCD) and electrochemical impendence spectroscopy (EIS). The highest specific capacitance of 1195 F/g has been obtained at a scan rate of 10 mV/s from hydrothermal synthesis nanomaterial electrode (J2) and long cycling life 92.3% retention after 2000th cycles. Furthermore, the energy density and power density of the J2 electrode at a current density of 5 A/g was 59 Wh/kg and 9234 W/kg, respectively. Hence, the fabricated J2 electrode is a favorable candidate for super-capacitor applications.
机译:镧系元素铁氧体纳米颗粒首次通过水热和共沉淀法合成。使用X射线粉末衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM)和能量分散X射线光谱(EDX)检查纳米颗粒的结构和形态学研究。使用循环伏安法(CV),GAL - 虚拟电解放电(GCD)和电化学封闭光谱(EIS),在6M KOH电解质中使用三个电极系统检查了J1和J2电极的电化学研究。 1195f / g的最高比电容以10mV / s的来自水热合成纳米材料电极(J2)和长循环寿命的长循环在循环后的长循环寿命。此外,J2电极的电流密度为5a / g的能量密度和功率密度分别为59wH / kg和9234w / kg。因此,制造的J2电极是用于超级电容器应用的有利候选者。

著录项

  • 来源
    《Journal of materials science》 |2021年第6期|7443-7454|共12页
  • 作者单位

    Department of Physics University of Gujrat Hafiz Hayat Campus Gujrat 50700 Pakistan;

    Department of Physics University of Gujrat Hafiz Hayat Campus Gujrat 50700 Pakistan Research Centre of Materials Science School of Material Science and Engineering Beijing Institute of Technology Beijing 100081 People's Republic of China;

    Catalysis and Nanomaterials Lab 27 Department of Chemistry Quaid-I-Azam University Islamabad 45320 Pakistan;

    Department of Physics University of Gujrat Hafiz Hayat Campus Gujrat 50700 Pakistan;

    Department of Chemical Engineering University of Gujrat Hafiz Hayat Campus Gujrat 50700 Pakistan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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