Geology, mineralization, and fluid inclusion characteristics of the Kashkasu W-Mo-Cu skarn deposit associated with a high-potassic to shoshonitic igneous suite in Kyrgyzstan, Tien Shan: Toward a diversity of W mineralization in Central Asia

摘要

Graphical abstractDisplay OmittedHighlights•The deposit is an example of the oxidized-type skarn related to high-K to shoshonitic igneous suite.•Two major stages of scheelite and sulfide deposition occurred.•Fluid evolution included cyclic releases of low- to high-salinity fluids from crystallizing magma.•Fluid boiling contributed to most intense scheelite deposition.•Fluids responsible for scheelite deposition were also Ca-rich, with multiple sources of Ca.AbstractThe Kashkasu deposit is part of the subduction-related Late Paleozoic (Late Carboniferous) metallogenic belt of Tien Shan. It is associated with a multiphase monzodiorite-monzonite-granodiorite-granite pluton of the magnetite-series high-K calc-alkaline to shoshonitic igneous suite. The deposit contains zones of W-Mo-Cu oxidized prograde and retrograde skarns, with abundant andraditic garnet, magnetite, locally scapolite and K-feldspar, as well as scheelite, chalcopyrite, and molybdenite. Skarns are overprinted by quartz-carbonate-sericite (phyllic alteration) zones with scheelite and sulfides.Prograde calcic skarn and initial retrograde skarns were formed from a high temperature (650 °C to 450–550 °C), high pressure (2000 bars to 600–900 bars) magmatic-hydrothermal low- to high-salinity aqueous chloride fluid. The gradual fluid evolution was interrupted by the intrusion of granodiorite and likely associated release of low-salinity (∼7–8 wt% NaCl equiv.) fluid. Ascent of this fluid to shallower levels and/or its cooling to 400–500 °C has resulted in phase separation into low-salinity (2.1–3.1 wt% NaCl equiv.) vapor and coexisting brine (35–40 wt% NaCl equiv.). The boiling was coincident with most intense scheelite deposition in retrograde skarn. Later retrograde skarn assemblages were formed from a gaseous, low- to moderate-salinity (3.4–8.1 wt% NaCl equiv.) fluid and then from high salinity (37–42 wt% NaCl equiv.) aqueous chloride fluids, the latter being enriched in Ca (17–20 wt% CaCl2) that could also affect scheelite deposition. Another cycle of fluid exsolution from crystallizing magma corresponded to quartz-carbonate-sericite-scheelite-sulfide (phyllic) alteration stage, with the early low-salinity (5.3–8.4 wt% NaCl-equiv.) fluid followed by later high-salinity (33.5–38.2 wt% NaCl-equiv.) fluid. The sulfur isotope data (δ34S = +5.1 to +9.0) suggest significant sulfur sourcing from sedimentary rocks enriched in seawater sulfate, possibly evaporites.