Vapor-phase deposition of regioregular and oriented poly(3-hexylthiophene) structures and novel nanostructured composites of interpenetrating poly(3-hexylthiophene) and poly aniline exhibiting full-color wavelength (400-1000 nm) photoluminescence

摘要

A promising solvent-free technique of electron-beam-assisted vapor-phase codeposition method is presented which allows uniform blending of different conjugated and nonconjugated polymers at the nanoscale. The technique allows direct incorporation of regioregular poly(3-hexylthiophene) (P3HT) polymer with different structural orientations into conventional and semiconducting polymers without fractionation or degradation of P3HT while maintaining the nanoscale morphology of deposited organic films. The results of fabricated novel nanostructured organic composites (～100-200 nm) comprising regioregular and oriented P3HT and different conjugated and nonconjugated polymers including selective assembly of P3HT nanonodules into a copolymer template are presented. We show a typical example of blending of P3HT and polyaniline (PANI) that formed a unique nanoscale morphology comprising interpenetrating networks of different shapes and sizes of nanospherulites (～100nm) of P3HT in PANI. The so fabricated nanocomposites (～200 nm) exhibited remarkable broadband photoluminescence features covering the entire blue, green, and red wavelength regions between 400 and 1000 nm. Such organic nanocomposites might be useful for flexible full-color screen flat panel displays and organic white-light solid-state lighting applications.