New markers of natural and anthropogenic chemical alteration of archaeological lignin revealed by in situ pyrolysis/silylation-gas chromatography-mass spectrometry

摘要

Analytical pyrolysis coupled with gas chromatography and mass spectrometry with in situ silylation using hexamethyldisilazane (Py(HMDS)-GC/MS) was used to investigate the chemical alteration patterns of a set of archaeological waterlogged oak and silver fir woods. The samples were collected from five piles removed from stilt houses found in a Neolithic village (Bracciano lake, Rome, Italy) and from various parts of the roof of a Roman house (Herculaneum, Italy).