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Preparation and Reactivity of Solvated Distonic Ions and Ionized Enols in the Gas Phase

机译:气相中溶剂化离子和离子型烯醇的制备及反应性

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摘要

Apart from ligand exchange, solvated species often give the same reactions as the corresponding, naked ions, but (as outlubed above) their reactivity can also be different. One aspect of the observed differences is that stabilization of the system by H_2O loss can be used to trap intermediates. Other aspects are the subject of a continuing investigation.
机译:除配体交换外,溶剂化物质通常会产生与相应的裸离子相同的反应,但(如上所示)其反应性也可能不同。所观察到的差异的一方面是由H_2O损失引起的系统稳定可用于捕获中间体。其他方面是不断调查的主题。

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