Hydroge-Bonded Porphyrinic Solids: Supramolecular Networks of Octahydroxy Porphyrins

摘要

Symmetrically substituted octahydroxy porphyrins, tetrakis(3', 5'-dihydroxyphenyl)porphyrin, H_2T(3',5'- DHP)P, tetrakis (2', 6'-dihydroxyphenyl)porphyrin H_2T(2',6'-DHP)P, and their Zn(Ⅱ) and Mn(Ⅲ) derivatives have been developed as building blocks for supramolecular hydrogen-bonded networks. The crystal structures of a series of these porphyrins exhibit unique structural features through assembly of porphyrin networks by means of directional hydrogen bonding.