Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes

Johann Bosson

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Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes

机译：16-电子钌配合物介导的手性醇外消旋化机理

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Experimental and computational analyses provide support for the existence of a metal-hydride-based mechanism for the ruthenium-mediated racemization of chiral alcohols.

机译：实验和计算分析为钌介导的手性醇消旋作用的金属氢化物机理的存在提供了支持。

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《Journal of the American Chemical Society》 |2010年第38期|p.13146-13149|共4页
作者
Johann Bosson;
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作者单位

EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews KY16 9ST, U.K., Catalan Institute for Water Research (ICRA), H2O Building, Scientific and Technological Park of the University of Girona, Emili Grahit 101, E-17003 Girona, Spain, and Dip;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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入库时间 2022-08-18 00:50:24

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专利

1. Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes [J] . Johann Bosson, Albert Poater, Luigi Cavallo, Journal of the American Chemical Society . 2010,第38期

机译：16-电子钌配合物介导的手性醇外消旋化机理
2. Mechanistic Aspects of Formation of Chiral Ruthenium Hydride Complexes from 16-Electron Ruthenium Amide Complexes and Formic Acid:Facile Reversible Decarboxylation and Carboxylation [J] . Takashi Koike, Takao Ikariya Advanced synthesis & catalysis . 2004,第1期

机译：由16电子钌酰胺配合物和甲酸形成手性氢化钌配合物的机理方面：易逆的脱羧和羧化反应
3. Mechanistic Aspects of Formation of Chiral Ruthenium Hydride Complexes from 16-Electron Ruthenium Amide Complexes and Formic Acid: Facile Reversible Decarboxylation and Carboxylation [J] . Takashi Koike, Takao Ikariya Advanced synthesis & catalysis . 2004,第1期

机译：由16-电子钌酰胺配合物和甲酸形成手性氢化钌配合物的机理方面：容易可逆的脱羧和羧基化
4. Racemic but Tropos (Chirally Flexible) BIPHEP Ligands for Rh(l)-Complexes: Highly Enantioselective Ene-Type Cyclization of 1,6-Enynes [C] . Shohei Kataoka, Kohsuke Aikawa, Koichi Mikami Symposium on Organometallic Chemistry . 2004

机译：Rh（L）的外消旋物但Tropos（手套柔性）Biphep配体 - 复用：1,6-inynes的高度映射烯型环化
5. I. Ground-state association between phenothiazine and tris(diimine)ruthenium(II) complexes: Its role in highly efficient photoinduced charge separation. II. Ligand modifications of cobalt complexes to increase efficiency of electron-transfer mediators in dye-sensitized solar cells [D] . Weber, John 2012

机译：一，吩噻嗪与三（二亚胺）钌（II）配合物之间的基态缔合：在高效光诱导电荷分离中的作用。二。钴配合物的配体修饰，以提高染料敏化太阳能电池中电子转移介体的效率
6. Mechanism of the Enantioselective Oxidation of Racemic Secondary Alcohols Catalyzed by Chiral Mn(III)–Salen Complexes [O] . M. Kevin Brown, Megan M. Blewett, James R. Colombe, -1

机译：外消旋的仲醇催化的对映选择性氧化通过手性的mn（III）配合物-salen的机制
7. Reaction of 16-Electron Ruthenium and Iridium Amide Complexes with Acidic Alcohols: Intramolecular C-H Bond Activation and the Isolation of Cyclometalated Complexes [O] . -1

机译：16 - 电子钌和铱酰胺配合物的反应与酸性醇：分子内C-H键活化和环级晶体化复合物的分离

Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes

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