Investigation of the electrocatalytic activity of metalophthalocyanine complexes for hydrogen production from water

摘要

The electrocatalytic proton reduction activity of metallophthalocyanines was investigated by using Nafion (Nf) membrane on ITO electrode embedding different metallophthalocyanine derivatives such as cobalt phthalocyanine (CoPc) and palladium phthalocyanine (PdPc) carrying tetra tricarbetoxyethyl groups. Electrocatalytic studies of CoPc indicated that the proton reduction was catalyzed by the CoPc via the electroreduced Co~ⅠPc(-2) or Co~ⅠPc(-1). PdPc modified ITO electrode exhibited only one cathodic wave which can be easily attributed to the proton reduction. Comparison of this wave with the bare electrode indicates that the complex does not work as a catalyst for proton reduction. Analysis of the CVs of CoPc at different pHs indicates that activity of CoPc varies arbitrarily with increasing pH. The most successful activity is at pH 2.2.