Long-term tests of a Jiilich planar short stack with reversible solid oxide cells in both fuel cell and electrolysis modes

摘要

A two-cell planar stack in the Jiilich F-design with solid oxide cells has been built and the reversible operation between fuel cell and electrolysis modes has been demonstrated. The cells were anode supported cells (ASC) with yttria-stabilized zirconia (YSZ) electrolytes, Ni/ YSZ hydrogen electrodes and perovskite oxygen electrodes with lanthanum strontium cobalt ferrite (LSCF). This paper summarizes and discusses the preliminary experimental results on the long-term aging tests of the reversible solid oxide planar short stack for fuel cell operation (4000 h) at a current density of 0.5 A cm~2 which shows a degradation of 0.6% per 1000 h and for steam electrolysis operation (3450 h) and co-electrolysis operation of CO_2 and H_2O (640 h) under different current densities from -0.3 to -0.875 A cm~(-2) which show different degradation rates depending on current density and on steam or co-electrolysis.