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Synthesize and characterization of ceria based nano-composite materials for low temperature solid oxide fuel cell

机译:低温固体氧化物燃料电池用二氧化铈基纳米复合材料的合成与表征

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摘要

The present study is focused on ceria based mixed (ionic and electronic conductor) composite Al0.05Ni0.1Ti0.05Zn0.80-SDC (ATZN-SDC) oxide material was prepared by solid state reaction, which can be used as anode materials for solid oxide fuel cell. The effect of Ti and Al oxides were analyzed on the NiZn-SDC composite with respect to its conductivity and catalytic activity in hydrogen atmosphere. The average crystallite size of the composite was found to be 40-100 nm by XRD and SEM. The DC conductivity was determined by 4-probe technique. The electrochemical impedance spectrum (EIS) was also examined in hydrogen atmosphere within a temperature range of 350-550 degrees C. The maximum power density 370 mW/cm(2) was achieved at 650 degrees C. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:本研究的重点是通过固相反应制备二氧化铈基混合(离子和电子导体)复合Al0.05Ni0.1Ti0.05Zn0.80-SDC(ATZN-SDC)氧化物材料,可用作固体阳极材料。氧化物燃料电池。分析了Ti和Al氧化物对NiZn-SDC复合材料在氢气氛中的电导率和催化活性的影响。通过XRD和SEM发现复合物的平均微晶尺寸为40-100nm。直流电导率通过四探针技术确定。还在350-550摄氏度的温度范围内的氢气氛中检查了电化学阻抗谱(EIS)。在650摄氏度下实现了最大功率密度370 mW / cm(2)。(C)2018 Hydrogen Energy Publications LLC 。由Elsevier Ltd.出版。保留所有权利。

著录项

  • 来源
    《International journal of hydrogen energy》 |2018年第12期|6310-6317|共8页
  • 作者单位

    Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, CAS Key Lab Magnet Mat & Devices, Ningbo 315201, Zhejiang, Peoples R China;

    Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, CAS Key Lab Magnet Mat & Devices, Ningbo 315201, Zhejiang, Peoples R China;

    Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, CAS Key Lab Magnet Mat & Devices, Ningbo 315201, Zhejiang, Peoples R China;

    COMSATS Inst Informat Technol, Dept Phys, Lahore 5400, Pakistan;

    COMSATS Inst Informat Technol, Dept Phys, Lahore 5400, Pakistan;

    COMSATS Inst Informat Technol, Dept Phys, Lahore 5400, Pakistan;

    KTH, Dept Energy Technol, S-10044 Stockholm, Sweden;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Nanocomposite anode; Nanostructure; Non-symmetrical fuel cell; LTSOFC; NiZn-SDC composite;

    机译:纳米复合阳极纳米结构非对称燃料电池LTSOFC NiZn-SDC复合材料;
  • 入库时间 2022-08-18 00:18:12

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