Hydrogen storage properties of new A_3B_2-type TiZrNbCrFe high-entropy alloy

摘要

Crystal structure and hydrogen storage properties of a novel equiatomic TiZrNbCrFe high entropy alloy (HEA) were studied. The selected alloy, which had a A3B2-type configuration (A: elements forming hydride, B: elements with low chemical affinity with hydrogen) was designed to produce a hydride with a hydrogen-to-metal atomic ratio (H/M) higher than those for the AB(2)- and AB-type alloys. The phase stability of alloy was investigated through thermodynamic calculations by the CALPHAD method. The alloy after arc melting showed the dominant presence of a solid solution C14 Laves phase (98.4%) with a minor proportion of a disordered BCC phase (1.6%). Hydrogen storage properties investigated at different temperatures revealed that the alloy was able to reversibly absorb and fully desorb 1.9 wt% of hydrogen at 473 K. During the hydrogenation, the initial C14 and BCC crystal structures were fully converted into the C14 and FCC hydrides, respectively. The H/M value was 1.32 which is higher than the value of 1 reported for the AB(2)- and AB-type HEAs. The present results show that good hydrogen storage capacity and reversibility at moderate temperatures can be attained in HEAs with new configurations such as A(3)B(2)/A(3)B(2)H(7). (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.