Numerical investigation into the decoupling effects of hydrogen blending on flame structure and soot formation in a laminar ethylene diffusion flame

摘要

Numerical calculations were conducted to explore the various effects of hydrogen blending on flame properties and soot behaviors in an ethylene coflow diffusion flame, based on a fully step-by-step decoupling method, by introducing several virtual species into the gas-phase mechanism. Results show that the concentration of OH increases under the chemical effect of hydrogen due to an enhanced rate of H-2 + O - OH + H. The soot yield, primary number density, and average primary number per aggregate decrease under dilution effect while these increase under chemical effect. The enhancements of hydrogen-abstraction-carbon-addition (HACA) rates and polycyclic aromatic hydrocarbon (PAH) condensation rates are responsible for soot mass addition under chemical effect. Both the oxidation rates by O-2 and OH are delayed under the chemical effect because of lower concentrations of O-2 and OH in the sooting zone. The overall effect of higher surface growth rates and delayed oxidation rates results in an increased soot volume fraction (SVF). (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.