Effect of nanoparticle aggregation on the thermal radiation properties of nanofluids: an experimental and theoretical study

摘要

Nanofluids show significant enhancement in the absorption of solar energy. However, little work has been done on the effect of nanoparticle aggregation on the thermal radiation properties of nanofluids up to now. In this work, we systematically investigate the thermal radiation properties of nanofluids with nanoparticle aggregation from experiment and theory. On the experimental side, titanium dioxide/silver (TiO_2@Ag) plasmonic nanofluids are prepared in distilled water and the spectral transmittance of nanofluids with different degrees of aggregation is measured. The result shows that the size of aggregated nanoparticle cluster has a significant effect on the absorption of nanofluids. On the theoretical side, a theoretical model is developed to calculate the thermal radiation properties of nanofluids with nanoparticle aggregation. By applying the multiple sphere T-matrix (MSTM) method and the Monte Carlo (MC) method, we investigate the effects of nanoparticle aggregation, cluster fractal dimensions and cluster sizes on the thermal radiation properties of nanofluids. The results indicate that our theoretical model can predict the thermal radiation properties of nanofluids with nanoparticle aggregation more reasonably. This is of great significance to understand the mechanism that affects the thermal radiation properties of nanofluids and to actively design nanofluids.