Synthesis and Characterization of Ce~(3+) :YAG Phosphors by Heterogeneous Precipitation Using Different Alumina Sources

摘要

Ce~(3+)-doped yttrium aluminum garnet (Ce:YAG) phosphor powders were synthesized by heterogeneous precipitation process using three different aluminum sources: α-phase, θ-phase, and boehmite (A1OOH). Mixtures of yttrium and cerium nitrate solutions containing various aluminum sources were precipitated by ammonia solution in normal and reverse strike methods. The influence of pH was studied in the normal strike method by maintaining the solutions at pH 7, 9, and 11 during precipitation. Dried precipitates were double calcined at 1300℃/l6 h and 1300-1500℃/24 h, at a ramping rate of 10℃/min, with an intermittent wet ball milling in water. Structural evolution of the resultant phosphors was studied by powder XRD. In the normal strike method, a highly pure YAG phase was formed by a- alumina (pH 7, 11) and 9-alumina (pH 11) while boehmite source ended up with mixed phases of YAlO_3 (YAP) and Y_4Al_2O_9 (YAM) along with YAG phase at all pH values of precipitation. However, in the reverse strike process, the 6-phase of alumina gave an extremely pure Ce:YAG phase at a relatively lower calcination temperature (l400℃/24h) compared with the a-phase and also showed more intense emission of yellowish-green light under blue (λ = 469 nm) excitation. Scanning electron microscopy revealed 1-2 μm sized particles with least agglomeration in the reverse strike method.