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HEAVY METALS MEASUREMENT: A SUITABLE SOLUTION TO IMPROVE ONLINE MEASUREMENT CELERITY

机译:重金属测量:一种提高在线测量可靠性的合适解决方案

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摘要

This article presents a low-cost, voltammetry-based measuring system to identify heavy metals dissolved in water and to evaluate their concentrations. The main objective of the proposed measurement system is related with measurements’ celerity. A segmented voltage sweep mode is proposed to overcome the slowness that is inherent to the use of the traditional continuous voltage sweep mode used in anodic striping voltammetry. The segmented voltage sweep is performed around the voltammetric current peaks that are associated with the heavy metals with higher concentrations or around voltage ranges that are associated with specific metals’ redox potentials. A solution to improve measurement celerity by reducing the time needed to remove the dissolved oxygen contained in the water sample is also presented. The article also includes the presentation of two self-test modes and several experimental results to evaluate the performance of the proposed measurement method.View full textDownload full textKeywordselectrochemical analysis, heavy metals measurement, measurement celerity, self-test, voltammetryRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/10739149.2012.673201
机译:本文提出了一种基于伏安法的低成本测量系统,可识别溶解在水中的重金属并评估其浓度。提议的测量系统的主要目标与测量的速度有关。为了克服阳极剥离伏安法中使用的传统连续电压扫描模式所固有的缓慢性,提出了分段电压扫描模式。分段电压扫描在与较高浓度重金属相关的伏安电流峰值附近或与特定金属的氧化还原电势相关的电压范围附近执行。还提出了通过减少去除水样中所含溶解氧所需时间来提高测量速度的解决方案。本文还介绍了两种自检模式和几种实验结果,以评估所提出的测量方法的性能。查看全文下载全文关键词电化学分析,重金属测量,测量速度,自检,伏安法相关var addthis_config = {ui_cobrand :“ Taylor&Francis Online”,services_compact:“ citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more”,pubid:“ ra-4dff56cd6bb1830b”};添加到候选列表链接永久链接http://dx.doi.org/10.1080/10739149.2012.673201

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