Environmental geochemistry at Red Mountain, an unmined volcanogenic massive sulphide deposit in the Bonnifield district,Alaska Range, east-central Alaska

摘要

The unmined, pyrite-rich Red Mountain (Dry Creek) deposit displays a remarkable environmental footprint of natural acid generation, high metal and exceedingly high rare earth element (REE) concentrations in surface waters. The volcanogenic massive sulphide deposit exhibits well-constrained examples of acid-generating, metal-leaching, metal-precipitation and self-mitigation (via co-precipitation, dilution and neutralization) processes that occur in an undisturbed natural setting, a rare occurrence in North America. Oxidative dissolution of pyrite and associated secondary reactions under near-surface oxidizing conditions are the primary causes for the acid generation and metal leaching. The deposit is hosted in Devonian to Mississippian felsic metavolcanic rocks of the Mystic Creek Member of the Totatlanika Schist.