Hydrogen transport and trapping in the GlidCop A125 IG alloy

摘要

The hydrogen properties of permeability, diffusivity and Sieverts' constant in the GlidCop A125 IG alloy have been experimentally evaluated by using the gas permeation technique. The experimental temperature range used has been from 573 K to 793 K and the high purity hydrogen loading pressures from 10~3 Pa to 1.5 × 10~5 Pa. The resultant diffusive transport parameters are a permeability of Φ (mol m~(-1) Pa~(-1/2) s~(-1)) = 5.87 × 10~(-7) exp(-80.kJ mol~(-1)/RT), a diffusivity of D (m~2 s~(-1)) = 5.70 × 10~(-5) exp(-76.8 kJ mol~(-1)/RT) and a Sieverts' constant of K_s (mol m~(-3) Pa~(-1/2)) = 6.01 × 10~(-3) exp(-3.7 kJ mol~(-1)/RT). The resultant trapping parameters area trap density of N_t = 3.1 × 10~(22) m~(-3) and a trapping energy of E_t = 75.4 kJ mol~(-1).The presence of ultrafine Al_2O_3 particles in this material has been demonstrated to affect enormously the hydrogen isotope transport behaviour in comparison to the corresponding base material (Cu) and other copper alloys. Hydrogen trapping phenomenon has become more noticeable in the lower temperature range, yielding an exothermic absorption of hydrogen below 688 K and a decrease in the effective hydrogen diffusivity.