Induced optical absorption of silicate glasses due to gamma irradiation at high temperatures

摘要

Gamma radiation-induced optical absorption in 75SiO_2-22Na_2O-3CaO (wt.%) multi-component glass and in the same glass additionally doped with 0.05 wt.% CeO_2 has been studied, with irradiations performed at 70,200, and 350℃, 25 kGy/h up to a dose of 0.6 MGy. For the undoped glass irradiation at 70℃ produces strong optical absorption from 700 nm down to the UV. Irradiation at 200℃ gives a lower level of optical absorption with a similar band composition. No induced optical absorption has been detected after irradiation at 350℃. Annealing at 200℃ for 24 h completely suppresses the induced optical absorption. Introduction of cerium increases the level of induced absorption in the UV range for irradiation at 70℃, and also creates bands stable up to 350℃. The results show that silica and sapphire, which are considered as main candidate materials for ITER diagnostic windows and other optical components, can potentially be complemented with multi-component silicate glasses. These materials may allow one to control the radioluminescence, and in addition provide a range of refractive indices required for achromatic lenses.