Removal of black carbon particles from experimental flue gas by surfactant solution in a new type of umbrella plate scrubber

摘要

Black carbon (BC) particles were removed from experimental flue gas by the surfactant solutions of sodium dodecylbenzene sulfonate (SDBS), hexadecyl trimethyl ammonium bromide (CTAB), fatty alcohol polyoxyethylene ether-9 (AEO-9) and polyoxy ethrlene nonyl phinyl ether-10 (TX-10), as well as AEO-9-SDBS, AEO-9-CTAB and SDBS-CTA$2 in a new type of umbrella plate scrubber. Among the four independent surfactants, AEO-9 has the lowest surface tension, 35.9 mN/m, which resulted in the highest BC removal ratio among the alone surfactants. The experimental conditions were as follows: dust concentration = 3000 mg/m~3; gas velocity =14 m/s; liquid-gas ratio = 0.801/m~3; and gas flow = 400 m~3/h. When the mole ratio of the mixed surfactants was 1:1, the lowest surface tension could be detected among the studied mixed surfactants. According to the molecular interaction parameters (β) and the mole ratio of surfactant 1 in the mixture (χ_1), the synergistic effects of AEO-9-SDBS and SDBS-CTAB solutions were obviously higher than those of AEO-9-TX-10 and AEO-9-CTAB. Therefore, AEO-9-SDBS solution had the lowest surface tension among the mixtures due to its p < 0 and χ-1 = 0.85. The mixture solution of AEO-9-SDBS (1:1 mole ratio, 0.2 mmol/1) yielded the highest BC removal ratio, about 99.8%, and it was about 12% higher than that of only water, which was about 87.9%. The calculated critical micelle concentration was almost the same as that of the experimental concentration when the related equation was corrected by β.