Effect of operating temperature on transient behaviour of a biofilter treating waste-air containing n-butanol vapour during intermittent loading

摘要

Transient-state removal of n-butanol vapour was investigated in a biofilter (BF) packed with compost and lava rock at different operating temperatures in the range of 30-45 degrees C under intermittent loading (8 h per day). Adsorption on the inactive bed and biodegradation in the microbial-active bed were studied separately at an empty bed residence time (EBRT) of 1 min and inlet concentrations of 2.6-3.2 g m(-3), respectively. According to the transient experiments, the highest removal efficiency (RE) around 86% was obtained at 40 degrees C due to a high microbial activity. Comparison of CO2 production and pure adsorption of n-butanol showed that adsorption was the major mechanism in the start-up of BF at each operating condition; although the impact of adsorption declined as temperature increased from 30 degrees C to 45 degrees C. The process was reaction limited at all operating conditions. Based on the determination of stoichiometric coefficients of n-butanol biodegradation, the CO2 production level was significantly lower than that of the chemical oxidation process which resulted in a decrease in environmental pollution.