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Enhanced simulated sunlight-driven photocatalytic performance of SnWO_4 prepared in the presence of cetyltrimethylammonium bromide

机译:在十六烷基三甲基溴化铵存在下制备的SnWO_4的增强的模拟阳光驱动光催化性能

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In this paper, SnWO_4 photocatalyst with enhanced simulated sunlight-driven photo-catalytic performance was prepared by a hydrothermal method in the presence of cetyltrimethylammonium bromide (CTAB). The samples were characterized by Brunauer-Emmett-Teller method, X-ray diffraction, UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, surface photovoltage spectroscopy, and scanning electron microscopy. The active free radicals formed were investigated by electron spin resonance spectroscopy and trapping experiments. Photocatalytic abilities of the photocatalyts were evaluated using methyl orange as model contaminant. The results show that CTAB induces redshift and promotes the photo-induced charge separation rate of SnWO_4, thereby boosting the photocatalytic performance. The photocatalytic test results reveal that the photocatalytic activity of CTAB-SnWO_4 is 7.25 times of the reference SnWO_4.
机译:本文在十六烷基三甲基溴化铵(CTAB)存在下,采用水热法制备了具有增强的模拟阳光驱动光催化性能的SnWO_4光催化剂。通过Brunauer-Emmett-Teller法,X射线衍射,UV-可见漫反射光谱,X射线光电子光谱,表面光电压光谱和扫描电子显微镜对样品进行表征。通过电子自旋共振光谱和捕获实验研究了形成的活性自由基。使用甲基橙作为模型污染物评估了光催化剂的光催化能力。结果表明,CTAB诱导红移并提高了SnWO_4的光诱导电荷分离率,从而提高了光催化性能。光催化测试结果表明,CTAB-SnWO_4的光催化活性是参比SnWO_4的7.25倍。

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