An experimental study of the impacts of solar radiation and temperature on mercury emission from different natural soils across China

摘要

Mercury (Hg) emission from natural soil is one of the most important contributors to global Hg cycles. Research on Hg emission from soil to air has been carried out in China. Currently, most of the research focuses on contaminated sites in China, while research in other regions is rare. To provide more accurate information on Hg emissions from soil to air in China and obtain additional laboratory data to verify the role of solar radiation and temperature in this process, we sampled and measured Hg emission fluxes from various natural soils (range, 48-240 ng/g) across mainland China under different solar radiation (0-900 W center dot m(-2)) and temperature (15-45 degrees C) conditions in a laboratory. We found that in different places in China, Hg emissions from natural soils occurred more easily when the soil Hg concentration, temperature, and solar radiation were high, but the impacts were different among the regions due to different soil types. Hg emissions from natural soils (0.071-24 ng center dot m(2)center dot h(-1)) were typically lower than those from contaminated sites, suggesting that additional measurements in natural soils are desirable. The results of this study could provide more accurate information on Hg emission from natural soil to air and help establish a nationwide natural soil Hg emission inventory in China.