All Solution-processed Stable White Quantum Dot Light-emitting Diodes with Hybrid ZnO@TiO₂ as Blue Emitters

摘要

White quantum dot light-emitting diodes (QD-LEDs) have been a promising candidate for high-efficiency and color-saturated displays. However, it is challenging to integrate various QD emitters into one device and also to obtain efficient blue QDs. Here, we report a simply solution-processed white QD-LED using a hybrid ZnO@TiO₂ as electron injection layer and ZnCdSeS QD emitters. The white emission is obtained by integrating the yellow emission from QD emitters and the blue emission generated from hybrid ZnO@TiO₂ layer. We show that the performance of white QD-LEDs can be adjusted by controlling the driving force for hole transport and electroluminescence recombination region via varying the thickness of hole transport layer. The device is demonstrated with a maximum luminance of 730?cd/m2 and power efficiency of 1.7?lm/W, exhibiting the Commission Internationale de l’Enclairage (CIE) coordinates of (0.33, 0.33). The unencapsulated white QD-LED has a long lifetime of 96?h at its initial luminance of 730?cd/m2, primarily due to the fact that the device with hybrid ZnO@TiO₂ has low leakage current and is insensitive to the oxygen and the moisture. These results indicate that hybrid ZnO@TiO₂ provides an alternate and effective approach to achieve high-performance white QD-LEDs and also other optoelectronic devices.