Optimization of As(Ⅲ) removal in hard water by electrocoagulation using central composite design with response surface methodology

摘要

Central composite design with response surface methodology was applied to optimize the main experimental parameters such as current, time, As(III) concentration, and hardness for arsenic (III) removal in hard water by the electrocoagulation process. The main aim was to find the optimum process parameters to maximize arsenic removal from the mathematical model equations developed in this study using R software. By variance and regression analysis, the linear regression equation was established as a predicted model. The R-2 of 0.93 indicated that the equation was well fitted. The optimum condition of 99% of As(III) removal for current (A), time (min), As(III) concentration (ppb), and hardness (mg/L as CaCO3) is 0.07, 37, 274, and 324, respectively. ANOVA analysis shows no significant difference between the observed and predicted values (p-value0.05) which shows good fit to the model.