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Removal of dibutyl phthalate (DBP) from aqueous solution by adsorption using vanillin- modified chitosan beads (CTSV)

机译:使用香草醛修饰的壳聚糖微珠(CTSV)吸附去除水溶液中的邻苯二甲酸二丁酯(DBP)

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摘要

To remove dibutyl phthalate from aqueous solution with vanillin-modified chitosan beads (CTSV), the environmental materials (chitosan and vanillin) were prepared by the green chemistry modification technology of microwave radiation. Compared with unmodified chitosan powders and beads, this new material CTSV was characterized with satisfied adsorption capacity by scanning electron microscope and Fourier translation transform-infrared analyses. Dynamics investigation and isothermal research were conducted to clarify the adsorption process of the CTSV. Results suggested that the adsorption process could be well described by Freundlich model. Meanwhile, dynamics investigation showed that the adsorption equilibrium could be reached after an hour and the correlative coefficient of pseudo-second-order kinetic model was 0.9333.
机译:为了用香草醛修饰的壳聚糖微珠(CTSV)从水溶液中去除邻苯二甲酸二丁酯,通过微波辐射的绿色化学修饰技术制备了环境物质(壳聚糖和香草醛)。与未改性的壳聚糖粉末和微珠相比,该新型材料CTSV通过扫描电子显微镜和傅立叶平移变换红外分析具有令人满意的吸附能力。进行了动力学研究和等温研究以阐明CTSV的吸附过程。结果表明,吸附过程可以用Freundlich模型很好地描述。同时,动力学研究表明,一小时后即可达到吸附平衡,拟二级动力学模型的相关系数为0.9333。

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