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A novel and inexpensive method for producing activated carbon from waste polyethylene terephthalate bottles and using it to remove methylene blue dye from aqueous solution

机译:一种从废聚对苯二甲酸乙二醇酯瓶中生产活性炭并用其从水溶液中去除亚甲基蓝染料的新颖且廉价的方法

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摘要

The current study aims to present a novel and inexpensive method for producing activated carbon using waste polyethylene terephthalate (PET) bottles in order to remove methylene blue (MB) dye from aqueous solution. Here, a novel method for producing activated carbon is developed by utilizing KOH and combining the carbonation and activation processes. Besides, the inert gases are not used in the production process. In order to determine the characteristics of the produced activated carbon texture, N-2 gas adsorption at 77K and scanning electron microscope are used. The adsorption isotherms of MB have been studied using Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin models. The specific surface area and the total volume of the generated activated carbon pores are 353.307m(2)/g and 0.288cc/g, respectively. In addition, q(max) for adsorption of MB dye is obtained as 404.089mg/g. Obtained results show that the Langmuir isotherm model has the best fitness. The values of R-2, the sum of squares of the errors percentage, and chi(2) for this model are measured as 0.996, 3.878, and 0.109, respectively. The present study shows that PET bottles are appropriate precursors for producing activated carbon. Besides, the present proposed method is effective and inexpensive.
机译:当前的研究旨在提出一种新颖且廉价的方法,该方法使用废对苯二甲酸乙二酯(PET)瓶生产活性炭,以便从水溶液中去除亚甲基蓝(MB)染料。在此,通过利用KOH并将碳酸化和活化过程相结合,开发了一种生产活性炭的新方法。此外,在生产过程中不使用惰性气体。为了确定所产生的活性炭织构的特性,使用在77K下的N-2气体吸附和扫描电子显微镜。 MB的吸附等温线已使用Langmuir,Freundlich,Dubinin-Radushkevich和Temkin模型进行了研究。生成的活性炭孔的比表面积和总体积分别为353.307m(2)/ g和0.288cc / g。另外,用于MB染料吸附的q(max)为404.089mg / g。所得结果表明,Langmuir等温模型具有最佳适应性。对于该模型,R-2的值,误差百分比的平方和和chi(2)的测量值分别为0.996、3.878和0.109。本研究表明,PET瓶是生产活性炭的合适前体。此外,本发明提出的方法是有效且廉价的。

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