Continuous chirality analysis of hexacoordinated tris-chelated metal complexes

摘要

We use the notion that symmetry can be evaluated on a continuous scale for the quantitative chirality analysis of tris-chelated metal complexes. After reviewing the Continuous Symmetry Measures methodology and its resulting Continuous Chirality Measure, we analyze the chiral- Ity of these complexes in terms of the specific contributions from the innermost ML_6 shell And from the ligand shells. The chirality behavior of seven families of tris(chelate)complexes Was analysed.