Corrosion and discharge performance of a magnesium aluminum eutectic alloy as anode for magnesium-air batteries

摘要

Magnesium aluminum eutectic alloy (Mg-34 % Al) was prepared as anode of magnesium-air battery with a view to decrease the corrosion rate of magnesium anode. Results indicate that as-cast eutectic alloy has a lower corrosion rate and a lower discharge activity in 3.5 % NaCl solution. The assembled battery with as-cast eutectic alloy as anode, a water soluble graphene poly (sodium 4-styrenesulfonate)/graphene based NaCl solution and a graphene/Mn3O4 nanometre composite as air cathode catalyst has a higher discharge activity. Lower corrosion rate of as-cast anode is due to corrosion products of black aluminum-rich oxide formed in fine lamella beta-Mg17Al12 phase.