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Corrosion inhibition efficiency of triethanolammonium dodecylbenzene sulfonate on Q235 carbon steel in simulated concrete pore solution

机译:三乙醇铵十二烷基苯磺酸盐对Q235碳钢在模拟混凝土孔隙溶液中的缓蚀作用

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The performance of triethanolammonium dodecylbenzene sulfonate (TDS), a type of cationic surfactant, against corrosion of Q235 carbon steel in an alkaline medium simulating concrete pore solution was studied by different electrochemical test methods. Electrochemical impedance spectroscopy (EIS) results revealed an increase in the charge transfer resistance of specimens in the presence of TDS, compared with the blank system. Both donor and acceptor density with the increase in TDS concentration, evident in the Mott-Schottky plots. Furthermore, observations using an optical microscope and the analysis of X-ray photoelectron spectroscopy measurements corroborated that the pitting corrosion of the metallic surface was significantly hindered with the addition of TDS into the simulated concrete pore solution.
机译:通过不同的电化学测试方法,研究了一种阳离子表面活性剂三乙醇铵十二烷基苯磺酸盐(TDS)在模拟混凝土孔隙溶液的碱性介质中对Q235碳钢的腐蚀性能。电化学阻抗谱(EIS)结果表明,与空白系统相比,存在TDS时样品的电荷转移电阻增加。在Mott-Schottky图中可以明显看出,供体和受体的密度都随TDS浓度的增加而增加。此外,使用光学显微镜进行的观察和X射线光电子能谱测量的分析证实了,将TDS添加到模拟混凝土孔隙溶液中后,金属表面的点蚀明显受到阻碍。

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