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Effect of ultraviolet aging on Theological properties of organic intercalated layered double hydroxides modified asphalt

机译:紫外线老化对有机插层双氢氧化物改性沥青流变学特性的影响

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摘要

The effect of ultraviolet (UV) aging on Theological properties of organic intercalated layered double hydroxides (OLDHs) modified asphalt was investigated by rotational viscosity and dynamic rheological properties. Experimental results indicate that the temperature susceptibility reflected by rotational viscosity and loss tangent of asphalt is decreased due to OLDHs, but the hardening caused by UV aging results in apparent decrease in temperature susceptibility of pristine asphalt, while the temperature susceptibility of OLDHs modified asphalt (OLMA) shows comparatively small decrement, exhibiting better UV aging resistance. Results of dynamic rheological properties show that the addition of OLDHs and LDHs increases the elastic component and rutting factor of asphalt binder at medium and high temperature, leading to a promotion of high temperature performance grade of asphalt. Owing to UV aging, the asphalt binder get stiffer and more brittle, which leads to more elastic behavior. However, the aging of OLMA are weakened for the smaller variations of rheological parameters as compared with pristine asphalt, which indicates excellent UV aging resistance of OLMA due to the introduction of OLDHs. Furthermore, OLDHs exhibit more effective modification than LDHs, which is due to the organic intercalation of LDHs that can improve the compatibility between LDHs and asphalt.
机译:通过旋转粘度和动态流变性能​​研究了紫外线(UV)老化对有机插层双层氢氧化物(OLDHs)改性沥青的流变学性能的影响。实验结果表明,OLDHs降低了沥青的旋转粘度和损耗角正切所反映的温度敏感性,而UV老化引起的硬化导致原始沥青的温度敏感性明显降低,而OLDHs改性沥青(OLMA)的温度敏感性)显示相对较小的减量,表现出更好的抗紫外线老化性能。动态流变性能​​的结果表明,OLDHs和LDHs的加入增加了沥青在中高温下的弹性成分和车辙系数,从而提高了沥青的高温性能等级。由于紫外线老化,沥青粘合剂变得更硬,更脆,这导致了更多的弹性行为。然而,与原始沥青相比,由于流变参数的变化较小,OLMA的老化作用减弱,这表明由于引入了OLDHs,OLMA具有出色的抗紫外线老化性能。此外,OLDHs表现出比LDHs更有效的修饰,这是由于LDHs的有机插入可以改善LDHs与沥青之间的相容性。

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