Synthesis and strength optimization of one-part geopolymer based on red mud

摘要

One-part geopolymer was synthesized from alkali-thermal activated Bayer red mud (RM) with addition of silica to optimize its composition. The RM was pretreated through alkali-thermal activation and turned to geopolymer precursor, which could be used by only adding water in blending process. However the long-term strength of the binder with only RM was poor because of the unstable polymerization due to the low SiO2/Al2O3 molar ratio (1.41). Silica fume (SF) was chosen to increase the SiO2/Al2O3 molar ratio of the geopolymer formulation. By adding 25 wt% of SF, the 28 d compressive strength of the geopolymer with a SiO2/Al2O3 molar ratio of 3.45 could reach 31.5 MPa at a water/solid ratio of 0.45. Sodium aluminosilicate in the activated RM dissolved in water and formed an alkaline environment to dissolve SF. The dissolved silica participated in geopolymerization, leading to a satisfactory geopolymer composition. Typical amorphous geopolymer matrices were formed in the binder completely cured. (c) 2016 Elsevier Ltd. All rights reserved.