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Effects of ammonium polyphosphate content on mechanical, thermal and flammability properties of kenaf/polypropylene and rice husk/polypropylene composites

机译:聚磷酸铵含量对洋麻/聚丙烯和稻壳/聚丙烯复合材料的机械,热学和可燃性的影响

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This study investigated the effects of ammonium polyphosphate (APP) content on the mechanical, thermal and flammability properties of kenaf/polypropylene (KF/PP) and rice husk/polypropylene (RH/PP) composites prepared by melt mixing technique. Polyethyleneoctene grafted maleic anhydride (POE-g-MAH) has been used as compatibilizer. The PP/KF/APP and PP/RH/APP composites were investigated using flexural and impact tests, scanning electron microscope, thermogravimetric analysis (TGA), differential scanning calorimeter and limiting oxygen index (LOI) test. Flexural modulus of PP/KF/APP and PP/RH/APP composites significantly improved from approximately 1.1-2.5 and 0.9-2.1 GPa, respectively, by the addition of 10 phr APP. The flexural strength of the composites also increased by the incorporation of 10 phr APP. In addition, the impact strength of the PP/RH/APP composites increased above 10 phr APP content. From the TGA results, incorporation of APP into PP/RH and PP/KF composites increased the char residue and thermal stability of the composites. Furthermore, the addition of APP increased the flame retardancy of the PP/ICF/APP and PP/RH/APP composites with a significant increase of LOI at 10 phr. (C) 2017 Elsevier Ltd. All rights reserved.
机译:这项研究调查了聚磷酸铵(APP)含量对通过熔融混合技术制备的洋麻/聚丙烯(KF / PP)和稻壳/聚丙烯(RH / PP)复合材料的机械,热学和可燃性的影响。聚乙烯辛烯接枝的马来酸酐(POE-g-MAH)已用作增容剂。使用弯曲和冲击测试,扫描电子显微镜,热重分析(TGA),差示扫描量热仪和极限氧指数(LOI)测试研究了PP / KF / APP和PP / RH / APP复合材料。通过添加10 phr APP,PP / KF / APP和PP / RH / APP复合材料的弯曲模量分别从约1.1-2.5 GPa和0.9-2.1 GPa显着提高。通过加入10phr APP也提高了复合材料的弯曲强度。另外,PP / RH / APP复合材料的冲击强度增加到10 phr以上。根据TGA结果,将APP掺入PP / RH和PP / KF复合材料中增加了炭渣和复合材料的热稳定性。此外,APP的添加提高了PP / ICF / APP和PP / RH / APP复合材料的阻燃性,LOI在10 phr时显着增加。 (C)2017 Elsevier Ltd.保留所有权利。

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