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Study on mechanical properties, thermal stability and crystallization behavior of PET/MMT nanocomposites

机译:PET / MMT纳米复合材料的力学性能,热稳定性和结晶行为研究

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PET/montmorillonite (MMT) nanocomposites were prepared via melt-blending and its nano-dispersion morphology was confirmed by X-ray diffraction and transmission electron microscopy. Its non-isothermal crystallization behavior was studied by DSC It is found that the crystallization rate of PET nanocomposite was increased significantly. The Avrami equation parameters related to crystallization, such as n, Z_c and t_(1/2), were calculated and analyzed. The thermal property and mechanical property of the composite were studied. When the MMT content was 1%, the composite has a desired comprehensive property. At this composition, the thermal degradation onset temperature and the thermal deformation temperature of PET were increased by 12 and 35℃, respectively, and the tensile strength of the PET was increased by 25% with slightly increase of the notched impact strength.
机译:通过熔融共混制备了PET /蒙脱土(MMT)纳米复合材料,并通过X射线衍射和透射电子显微镜证实了其纳米分散形态。通过DSC研究了其非等温结晶行为,发现PET纳米复合材料的结晶速率大大提高。计算和分析了与结晶有关的Avrami方程参数,例如n,Z_c和t_(1/2)。研究了复合材料的热性能和力学性能。当MMT含量为1%时,该复合材料具有所需的综合性能。在该组成下,PET的热降解起始温度和热变形温度分别增加了12℃和35℃,并且随着缺口冲击强度的略微增加,PET的拉伸强度增加了25%。

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