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Effects of aging on asphalt binders modified with microencapsulated phase change material

机译:时效对微胶囊相变材料改性沥青结合料的影响

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摘要

Temperature and chemical composition are governing parameters for the mechanical behavior of asphalt binders. During extreme low and high temperatures, asphalt binders can suffer thermal cracking as well as permanent deformation, respectively. The use of phase change materials (PCM) can provide asphalt binder with thermal energy storage properties for reducing the impacts of pavement temperature rise and decrease during seasonal and diurnal cycles. Studying the feasibility of using microencapsulated PCM in asphalt binders is the mean aim of this study. Accordingly, different penetration grade binders modified with microencapsulated PCM were characterized and their blends artificially aged using Rolling Thin Film Oven (RTFO) and Pressure Ageing Vessel (PAV) devices. This study also covers different size distributions of microcapsules. The thermal and rheological properties of both modified and unmodified asphalt binder under different aging conditions were analyzed using dynamic scanning calorimetry (DSC) and dynamic shear rheometer (DSR). It was found that the melting enthalpy of modified asphalt binder reduces upon aging and the reduction is dependent also on the type of binder. The results elucidate that the survival of microencapsulated PCM in asphalt binder depends on both the type of binder and the microcapsules used. Moreover, the rheological properties of modified asphalt binder determined with DSR improve due to the thermal energy released by PCM crystallization during cooling.
机译:温度和化学组成是沥青粘合剂机械性能的主要控制参数。在极端低温和高温下,沥青粘合剂可能会分别遭受热裂和永久变形。相变材料(PCM)的使用可以为沥青粘结剂提供热能存储特性,以减少季节和昼夜周期中路面温度升高和降低的影响。研究在沥青粘结剂中使用微囊化PCM的可行性是本研究的平均目标。因此,表征了用微囊化PCM改性的不同渗透等级的粘合剂,并使用滚动薄膜烤箱(RTFO)和压力老化容器(PAV)装置对它们的混合物进行了人工老化。这项研究还涵盖了微胶囊的不同大小分布。使用动态扫描量热法(DSC)和动态剪切流变仪(DSR)分析了改性沥青和未改性沥青在不同老化条件下的热和流变性能。已经发现,改性沥青粘合剂的熔融焓随着老化而降低,并且该降低还取决于粘合剂的类型。结果表明,沥青胶结剂中微囊化PCM的存留取决于胶结剂的类型和所使用的微胶囊。而且,由于冷却期间PCM结晶释放的热能,用DSR测定的改性沥青粘合剂的流变性能得以改善。

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