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High mechanical strength hydrogels preparation using hydrophilic reactive microgels as crosslinking agents

机译:使用亲水反应性微凝胶作为交联剂的高机械强度水凝胶制备

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摘要

HRM (hydrophilic reactive microgels) hydrogels based on acrylamide and 2-acrylamido-2-methylpropane sulfonic acid were prepared using HRM as a new crosslinking agent. HRM containing double bonds (C=C) were obtained by chemically modifying hydrophilic microgels (HM) of acrylamide with 2-acrylamido-2-methylpropane sulfonic acid. The resulting HRM hydrogels had high compression strength, elasticity, and elongation under high water content. The excellent mechanical performance is a main result of the unique microstructure of the hydrogels that are crosslinked by HRM instead of the conventional crosslinking agents such as N,N′–methylenebisacrylamide.
机译:以HRM为新型交联剂,制备了基于丙烯酰胺和2-丙烯酰胺基-2-甲基丙烷磺酸的HRM(亲水反应微凝胶)水凝胶。通过用2-丙烯酰胺基-2-甲基丙烷磺酸对丙烯酰胺的亲水性微凝胶(HM)进行化学修饰,可以获得含有双键(C = C)的HRM。所得的HRM水凝胶在高含水量下具有高压缩强度,弹性和伸长率。优异的机械性能是水凝胶独特的微观结构的主要结果,该水凝胶通过HRM代替了传统的交联剂(例如N,N'-亚甲基双丙烯酰胺)进行了交联。

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