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Photodegradation of Dyes in Aqueous Solutions containing Fe(Ⅲ) — hydroxy Complex: Ⅰ . Photodegradation Kinetics

机译:含Fe(Ⅲ)-羟基配合物的水溶液中染料的光降解:Ⅰ。光降解动力学

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摘要

The photodegradation of five dyes, C. I. reactive red 2, C. I. reactive blue 4, C. I. reactive black 8, C. I. basic red 13 and C. I. basic yellow 2, were studied in an UV/Fe(Ⅲ) — hydroxy system using a 30W UV disinfection lamp (λ_(max) = 253.7nm). Photodegradation for C. I. reactive 2, C. I. reactive blue 4 and C. I. basic red 13 were pseudo—first order reactions while the others were pseudo—zero order reactions. The effects of the initial concentrations of the dyes on reaction kinetics were studied.
机译:使用30W紫外线消毒灯在UV / Fe(Ⅲ)-羟基体系中研究了5种染料的反应活性:CI活性红2,CI活性蓝色4,CI活性黑色8,CI碱性红色13和CI碱性黄色2。 (λ_(max)= 253.7nm)。 C. I.反应性2,C。I.反应性蓝色4和C. I.基本红色13的光降解是伪一级反应,而其他是伪零级反应。研究了染料初始浓度对反应动力学的影响。

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