Concentrations and isotope ratios of mercury in sediments from shelf and continental slope at Campos Basin near Rio de Janeiro, Brazil

摘要

Mercury (Hg) may originate from both anthropogenic and natural sources. The measurement of spatial and temporal variations of Hg isotope ratios in sediments may enable source identification and tracking of environmental processes. In this study we establish the distribution of mercury concentrations and mercury isotope ratios in surface sediments of three transects along the continental shelf and slope in Campos Basin-RJ-Brazil. The shelf showed on average lower total Hg concentrations (9.2 +/- 5.3 ng g(-1)) than the slope (24.6 +/- 8.8 ng g(-1)). MMHg average concentrations of shelf 0.15 +/- 0.12 ng g(-1) and slope 0.13 +/- 0.06 ng g(-1) were not significantly different. Distinct differences in Hg isotope ratio signatures were observed, suggesting that the two regions were impacted by different sources of Hg. The shelf showed more negative delta Hg-202 and Delta Hg-199 values ranging from -0.59 to -2.19 parts per thousand and from -0.76 to 0.08 parts per thousand, respectively. In contrast, the slope exhibited delta Hg-202 values from -0.29 to 1.82 parts per thousand and Delta Hg-199 values from -0.23 to 0.09 parts per thousand. Mercury found on the shelf, especially along the "D" and "I" transects, is depleted in heavy isotopes resulting in more negative delta Hg-202 compared to the slope. Isotope ratios observed in the "D" and "I" shelf region are similar to Hg ratios commonly associated with plants and vegetation and very comparable to those detected in the estuary and adjoining mangrove forest, which suggests that Hg exported from rivers may be the dominating source of Hg in near coastal regions along the northern part of the shelf. (C) 2017 Elsevier Ltd. All rights reserved.