Lewis Acid Assisted Stabilization of Side-On Bonded N2 in [Ru(NCN)]-Pincer Complexes—Computational Catalyst Design Directed at NH3 Synthesis from N2 and H2

Dr. Markus Houml; lscher; Prof. Dr. Walter Leitner

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Lewis Acid Assisted Stabilization of Side-On Bonded N₂ in [Ru(NCN)]-Pincer Complexes—Computational Catalyst Design Directed at NH₃ Synthesis from N₂ and H₂

机译：路易斯酸辅助稳定[Ru（NCN）]-Piner配合物中侧键N _{2 的稳定化-直接用于N _{2合成NH _{3 的计算催化剂设计和H ₂}}}

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With a little help of my boron: Ruthenium pincer complexes with Lewis acidic side arms help to stabilize side-on coordinated N₂, which is necessary for catalytic reduction to NH₃ with H₂.

机译：在我的硼的帮助下：带有路易斯酸性侧臂的钌钳配合物有助于稳定侧向配位的N _{2 ，这对于将N _{3 催化还原为NH H _{2 。}}}

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《Chemistry - A European Journal》 |2010年第48期|p.14266-14271|共6页
作者
Dr. Markus Houml; lscher; Prof. Dr. Walter Leitner;
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正文语种 eng
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computational chemistry; density functional calculations; homogeneous catalysis; ammonia synthesis; pincer complexes;

机译：计算化学;密度泛函计算;均相催化;氨合成;钳形配合物;

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1. Lewis acid assisted stabilization of side-on bonded N_2 in [Ru(NCN)]-pincer complexes-Computational catalyst design directed at NH _3 synthesis from N_2 and H_2 [J] . H?lscher M., Leitner W. Chemistry: A European journal . 2010,第48期

机译：路易斯酸辅助稳定[Ru（NCN）]-钳配合物中侧键N_2的稳定性-针对由N_2和H_2合成NH _3的计算催化剂设计
2. Chiral nickel(II) and palladium(II) NCN-pincer complexes based on substituted benzene: Synthesis, structure, and lewis acidity [J] . Bugarin A, Connell BT Organometallics . 2008,第17期

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3. Synthesis of 2,6-Bis(2-oxazolinyl)phenylplatinum(II) NCN Pincer Complexes by Direct Cyclometalation. Catalysts for Carbon-Carbon Bond Formation [J] . John S.Fossey, Christopher J.Richards Organometallics . 2004,第3期

机译：直接环金属化合成2,6-双（2-恶唑啉基）苯基铂（II）NCN钳形配合物。碳-碳键形成的催化剂
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5. Investigation of Silicon Lewis acidity and design of a novel Silicon Lewis acid catalyst scaffold. [D] . Zielinski, Matthew Edward. 2014

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7. Novel silica immobilized NCN-pincer palladium(II) and platinum(II) complexes: Application as Lewis acid catalysts [O] . Mehendale, N.C., Bezemer, C., van Walree, C.A., 2006

机译：新型二氧化硅固定的NCN-钳形钯（II）和铂（II）配合物：用作路易斯酸催化剂

Lewis Acid Assisted Stabilization of Side-On Bonded N2 in [Ru(NCN)]-Pincer Complexes—Computational Catalyst Design Directed at NH3 Synthesis from N2 and H2

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Lewis Acid Assisted Stabilization of Side-On Bonded N₂ in [Ru(NCN)]-Pincer Complexes—Computational Catalyst Design Directed at NH₃ Synthesis from N₂ and H₂